HT GPC
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KOPTRI professionally measures the molecular weight of crystalline polymers in polyolefin group that are insoluble in room temperatures by utilizing High Temperature-GPC (Gel Permeation Chromatography).
Eluent used to measure the molecular weight of polyolefin for high-temperature GPC is TCB(1,2,4-trichlorobenzene). Mechanical properties of Polyethylene or polypropylene will significantly affected on its molecular weight, molecular weight distribution, and branching, which requires quality control with GPC. Please give us a separate inquiry for ultra-high molecular weight polyethylene with a molecular weight of over a million. If semiconducting polymers such as polythiophene (aromatic conjugated polymer) does not dissolve in chloroform, we use TCB-GPC to measure the molecular weight. If you need help with analysis, please send us a request by submitting ‘Application Form’ under ‘Contact Us’ tab, and supervising researcher will aid you with a punctual and meticulous reply.
HT-GPC setup
※ Use left and right scroll for tables
Polymers | MW range | Temperature | Standard | Detector |
LDPE HDPE LLDPE PP Polythiophene Conjugated Polymer |
500 ~ 3,000,000 Da |
160 ℃ | TCB | RI |
TCB: 1,2,4-trichlorobenzene
HT-GPC Chromatogram of Polystyrene standards (TCB)
HT-GPC Chromatogram of Polyethylene (TCB)
- Instrument : HLC-8321 GPC/HT
- Column (maker, model no.): PLgel guard + 2 x PLgel mixed-B
- Eluent : TCB (1,2,4-trichlorobenzene)
- Temperature : 160 ℃
- Flow rate : 1.0 mL/min
- Injection volume, sample concentration : 300 ㎕, 1.5 mg/mL
- Standard : Polystyrene
- Detector : RI